7/29/2023 0 Comments Quantum fluid dynamicsThe unphysical charge transfers are interpreted in terms of degeneracies in the spectrum of orbital energies of the aqueous acetone solution. The result of 0.19 eV is in good agreement with experiment, as is the general increase in the mean oscillator strength of the transition. The optically active occupied states are found to be largely localized on either solute or solvent, and using this feature we were again able to isolate the physical n→□* band and compute the solvatochromic shift. This analysis is then carried over to a solution of acetone in water, where further complications are encountered in the from of a solute→solvent charge transfer excitations overlapping with the n→□* band. The n→□* transition can be partially isolated from the charge-transfer bands, yielding a blueshift of 0.17 eV with respect to gas-phase acetone. The latter system is characterized by the appearance of relatively intense features in the low-energy region of the spectrum, attributable to spurious solvent →solute charge-transfer excitations created by deficiencies in the DFT methodology. The gain in intensity brought about by thermal fluctuations is studied in molecular acetone at room temperature, and in gas-phase ( CH3 ) 2 CO We propose a suitable formalism for computing transition intensities based on the modern theory of polarization, which is applicable to condensed-phase and finite systems alike. 118, 3928 □2003□□ is n→□* electronic applied to the study of solvent shift and intensity enhancement effects of the 1A transition in acetone, treating solute and solvent at the same level of theory. A recently introduced formulation of time dependent linear response density functional theory within the plane-wave pseudopotential framework □J.
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